I asume you are refering to the solenoid on the starter. It excites the solenoid windings causing the iron core to move, which moves attached linkage that moves the starter drive up into the flywheel and at the same time it bridges the contacts to provide the high amperage current flow to the starter motor. Think of it as a amplifier for increasing current flow. The slave solenoid does the same thing for the main solenoid.. Because of all wiring switches as well as heat from hot soaks the main solenoid can have intermittent failure to operate without the slave to give a little boost
Early GM vehicles used to have this issue I described, installing a slave corrected the problem. This was smart on Mercurys part to do it this way assuring the starter would still crank the motor when a battery is down considerably.